固体氧化物燃料电池宏观力学效应研究进展

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doi:10.6052/1000-0992-20-023

¹哈尔滨工业大学(深圳)机电工程与自动化学院, 广东深圳 518055
²哈尔滨工业大学(深圳)理学院, 广东深圳 518055

基金项目:

科技部重点研发计划 (2018YFB1502602); 国家自然科学基金重点项目 (11932005); 深圳市自然科学基金项目 (JCYJ20200109113439837) 资助.

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作者简介:
*E-mail: zhongzheng@hit.edu.cn
仲政, 哈尔滨工业大学(深圳)教授, 博士生导师, 理学院院长. 国家杰出青年科学基金获得者, 入选新世纪百千万人才工程国家级人选、上海市优秀学科带头人计划、上海市领军人才计划、深圳市国家级领军人才, 获得首届全国高校青年教师奖、国务院政府特殊津贴、中国科协"全国优秀科技工作者"称号. 担任教育部力学专业教学指导委员会副主任委员、开云棋牌官方固体力学专业委员会副主任委员. 曾任开云棋牌官方常务理事、上海市力学学会理事长. 主要研究方向为多场耦合力学、复合材料力学与结构、材料疲劳与断裂. 近年来, 重点开展了固体氧化物燃料电池的多场耦合研究.

通讯作者:
仲政

中图分类号:TM911.4
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出版历程
- 收稿日期:2020-09-22
- 刊出日期:2021-03-25

Progress in macro scale mechanical effects investigation of solid oxide fuel cells

¹Department of Mechanical Engineering and Automation, Harbin Institute of Technology, Shenzhen 518055, Guangdong, China
²School of Science, Harbin Institute of Technology, Shenzhen 518055, Guangdong, China

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Corresponding author:ZHONG Zheng

摘要

摘要:固体氧化物燃料电池(SOFC)是一种清洁高效且具有广泛应用前景的绿色发电装置. SOFC采用了陶瓷材料电极和电解质并在高温下工作, 力学损伤是造成其性能和寿命衰减的主要因素之一. 由于实验测试的局限性, 基于宏观力学模型的数值模拟是优化SOFC电池和电堆结构、提高其性能和耐久性的重要手段. 本文综述并评价了SOFC宏观力学效应的研究进展, 介绍了SOFC在制造、正常运行和长期工作的不同阶段受到的残余应变、阳极氧化应变、化学膨胀、工作热应变以及蠕变等力学效应. 总结了各种力学效应以及目前关注较少的电化力耦合效应的理论和数值模拟研究现状, 最后展望了SOFC宏观力学性能研究的发展前景.
- 固体氧化物燃料电池/
- 力学性能/
- 数值模拟/
- 耐久性/
- 电化力耦合
Abstract:Solid oxide fuel cell (SOFC) is a clean and high-efficiency electric power generation device with promising application prospects. The SOFC uses the ceramic material as electrodes and electrolytes. Due to its high working temperature, mechanical failure is one of the most significant factors leading to the decrease of SOFC performance and lifetime. In-situ experimental measurements are quite limited in SOFCs. Therefore, a numerical simulation based on macro-scale mechanical models is generally employed for structure optimization of a single cell and stack. Progress in macro-scale mechanical effects of SOFCs is reviewed in this study. The principles and mathematical models of mechanical effects include residual strain, oxidation strain, chemical expansion, thermal ain, and creep strain in different SOFC manufacturing and operating stages are introduced. The latest development in the theoretical study and numerical simulation on different mechanical effects, as well as the electro-chemo-mechanical coupling effects, are summarized. In the last, the prospects of macro-scale mechanical effects investigation of SOFCs are discussed.
- solid oxide fuel cell/
- mechanical properties/
- numerical simulation/
- lifetime/
- electro-chemo-mechanical coupling

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