锂离子电池硅负极材料衰退机理的研究进展

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doi:10.6052/1000-0992-13-066

1 湘潭大学低维材料及其应用技术教育部重点实验室, 湘潭大学材料与光电物理学院, 湘潭411105
2 中国科学院长春应用化学研究所, 长春130022
3 北京工业大学机电学院工程力学系, 北京100124

基金项目:国家自然科学基金（11102176, 11372267）；国家高技术研究发展计划（863 计划）（2013AA032502）；湖南省战略性新兴产业（2012GK4075）资助项目

详细信息

通讯作者:
周益春，潘勇
周益春，潘勇

中图分类号:TM912
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- 被引次数:0
出版历程
- 收稿日期:2013-09-01
- 修回日期:2013-10-22
- 刊出日期:2013-11-25

Research progress in degradation mechanism of silicon anode materials for lithium-ion batteries

1 Key Laboratory of Low Dimensional Materials and Application Technology of Ministry of Education, Faculty of Materials, Optoelectronics and Physics, Xiangtan University, Xiangtan 411105, China
2 State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
3 Department of Engineering Mechanics, Beijing University of Technology, Beijing 100124, China

Funds:The project was supported by the National Natural Science Foundation of China (11102176, 11372267), the National High Technology Research and Development Program of China (863 Program) (2013AA032502), and the Emerging Strategic Industries of Hunan Province (2012GK4075).

More Information

Corresponding author:ZHOU Yichun;PAN Yong

摘要

摘要:硅负极材料由于具有非常高的理论比容量，使之成为锂离子电池极具前景的负极替代材料，然而，硅负极材料在充放电过程中会发生非常大的体积变形，这会引起活性材料的破坏失效，严重影响其电化学循环性能，成为制约其在锂离子电池领域广泛应用的最大瓶颈，本文介绍了硅负极材料的不同结构形态及其在充放电过程中电化学性能的退化机理，并综述了充放电过程中的力学性能演化、相关理论分析、数值模拟计算等方面的最新国际研究进展，展望了硅负极材料力学失效方面的研究重点，
- 锂离子电池/
- 硅负极材料/
- 离子扩散/
- 应力演化/
- 数值模拟/
- 力--化耦合
Abstract:Silicon anode materials have very high theoretical specific capacity, hence become promising replacement for anode material of lithium-ion batteries. However, during charging and discharging, silicon anode materials suffer big volume deformation that may cause destruction and failure of the active material. This seriously affects the electrochemical cycle performance, and restricts wide applications in the field of lithium-ion batteries. In this paper, we introduce silicon anode materials of different structure form, and the degradation mechanism of the electrochemical properties during charging and discharging. We summarize the latest international research progress in mechanical properties evolution of charging and discharging process, the related theoretical analysis, numerical simulations, and prospects for research emphasis of the mechanical failure in silicon anode materials.
- lithium-ion battery/
- silicon anode materials/
- ion diffusion/
- stress evolution/
- simulations/
- chemo-mechanical coupling

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